Critical perspectives on metal–organic frameworks and their composites for the adsorptive removal of antibiotics from wastewater matrices

  • Antibiotics have recently emerged as a significant class of organic pollutants for ground and drinking water and have raised widespread concern due to their adverse environmental consequences. For instance, they stimulate the generation of antibiotic-resistant genes that have detrimental effects on the entire biosphere. The removal of these antibiotics from water matrices has always remained a daunting task. Metal–organic frameworks (MOFs) with a high surface area, tunable porosity, rich structural chemistry, and tailorability have grabbed immense attention recently for the efficient adsorptive removal of various antibiotics via strong host–guest interactions. Here, in this Perspective, we have rationally reviewed the state-of-the-art advancements of MOFs and their composites for the adsorptive removal of various antibiotic classes. Moreover, different strategies to improve the adsorption of antibiotics and the factors affecting the adsorption are critically presented. Various types ofAntibiotics have recently emerged as a significant class of organic pollutants for ground and drinking water and have raised widespread concern due to their adverse environmental consequences. For instance, they stimulate the generation of antibiotic-resistant genes that have detrimental effects on the entire biosphere. The removal of these antibiotics from water matrices has always remained a daunting task. Metal–organic frameworks (MOFs) with a high surface area, tunable porosity, rich structural chemistry, and tailorability have grabbed immense attention recently for the efficient adsorptive removal of various antibiotics via strong host–guest interactions. Here, in this Perspective, we have rationally reviewed the state-of-the-art advancements of MOFs and their composites for the adsorptive removal of various antibiotic classes. Moreover, different strategies to improve the adsorption of antibiotics and the factors affecting the adsorption are critically presented. Various types of antibiotics are categorically organized, and their removal with these systems is critically discussed. Advantages and pitfalls of MOFs over other classical porous materials are particularly stated from both academic and industrial viewpoints. Finally, the challenges and future outlook are discussed to guide further development of multifunctional MOF-based materials for the efficient adsorptive removal of various antibiotic classes.show moreshow less

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Metadaten
Author:Debolina Mukherjee, Janaki Behera, Supriya Mondal, Shyam Chand Pal, Dirk VolkmerORCiDGND, Madhab C. Das
Frontdoor URLhttps://opus.bibliothek.uni-augsburg.de/opus4/108688
ISSN:1528-7483OPAC
ISSN:1528-7505OPAC
Parent Title (English):Crystal Growth & Design
Publisher:American Chemical Society (ACS)
Type:Article
Language:English
Date of first Publication:2023/09/27
Release Date:2023/10/26
Tag:Condensed Matter Physics; General Materials Science; General Chemistry
Volume:23
Issue:11
First Page:7612
Last Page:7634
DOI:https://doi.org/10.1021/acs.cgd.3c00892
Institutes:Mathematisch-Naturwissenschaftlich-Technische Fakultät
Mathematisch-Naturwissenschaftlich-Technische Fakultät / Institut für Physik
Mathematisch-Naturwissenschaftlich-Technische Fakultät / Institut für Physik / Lehrstuhl für Festkörperchemie
Nachhaltigkeitsziele
Nachhaltigkeitsziele / Ziel 6 - Sauberes Wasser und Sanitäre Einrichtungen
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 53 Physik / 530 Physik