High‐strength Si–SiC lattices prepared by powder bed fusion, infiltration‐pyrolysis, and reactive silicon infiltration

  • This study focuses on the design, additive manufacturing, and characterization of silicon carbide-based components with complex geometries. These parts were produced using a novel hybrid technique, previously developed: powder bed fusion of polyamide was used to 3D print two different templates with complex architectures. Preceramic polymer infiltrations and pyrolysis with polycarbosilane and furan resin were performed to obtain the ceramic parts. The final densification was achieved with reactive or nonreactive silicon infiltrations according to four different strategies, producing ceramics comprised of crystalline βSiC, reaction-bonded βSiC, and low residual silicon. The final gyroid samples (∼70 vol% macroporosity) exhibited a maximum compressive strength of 24.7 ± 2.2 MPa, with a skeleton density of 3.173 ± 0.022 g/cm3, and a relative density of 0.935 ± 0.016. These findings underscore the potential of this manufacturing approach and showcase its effectiveness in fabricatingThis study focuses on the design, additive manufacturing, and characterization of silicon carbide-based components with complex geometries. These parts were produced using a novel hybrid technique, previously developed: powder bed fusion of polyamide was used to 3D print two different templates with complex architectures. Preceramic polymer infiltrations and pyrolysis with polycarbosilane and furan resin were performed to obtain the ceramic parts. The final densification was achieved with reactive or nonreactive silicon infiltrations according to four different strategies, producing ceramics comprised of crystalline βSiC, reaction-bonded βSiC, and low residual silicon. The final gyroid samples (∼70 vol% macroporosity) exhibited a maximum compressive strength of 24.7 ± 2.2 MPa, with a skeleton density of 3.173 ± 0.022 g/cm3, and a relative density of 0.935 ± 0.016. These findings underscore the potential of this manufacturing approach and showcase its effectiveness in fabricating intricate ceramic structures for engineering applications as heat exchangers and catalytic supports.show moreshow less

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Metadaten
Author:Marco Pelanconi, Samuele Bottacin, Giovanni Bianchi, Dietmar KochORCiDGND, Paolo Colombo, Alberto Ortona
Frontdoor URLhttps://opus.bibliothek.uni-augsburg.de/opus4/112051
ISSN:0002-7820OPAC
ISSN:1551-2916OPAC
Parent Title (English):Journal of the American Ceramic Society
Publisher:Wiley
Type:Article
Language:English
Year of first Publication:2024
Publishing Institution:Universität Augsburg
Release Date:2024/03/18
Tag:Materials Chemistry; Ceramics and Composites
DOI:https://doi.org/10.1111/jace.19750
Institutes:Mathematisch-Naturwissenschaftlich-Technische Fakultät
Mathematisch-Naturwissenschaftlich-Technische Fakultät / Institut für Materials Resource Management
Mathematisch-Naturwissenschaftlich-Technische Fakultät / Institut für Materials Resource Management / Lehrstuhl für Materials Engineering
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 50 Naturwissenschaften / 500 Naturwissenschaften und Mathematik
Latest Publications (not yet published in print):Aktuelle Publikationen (noch nicht gedruckt erschienen)
Licence (German):CC-BY 4.0: Creative Commons: Namensnennung (mit Print on Demand)