Structure of the carbazole Ar2 trimer from high resolution UV spectroscopy
- Highly resolved spectra of the 000 (S1←S0) transition of the carbazoleAr2 complex were measured by mass-selective resonance-enhanced two-photon ionization with a narrow-band pulsed laser (Δν<140 MHz). The parallel c-type rotational band structure displays regular sharp features which are used to find an accurate set of rotational constants of the trimer. From the experimental result a (2¦0) structure of the investigated complex with the two Ar atoms located on one side of the carbazole plane can be excluded. Two possible (1¦1) structures and consequences for the solvation mechanism are discussed.
| Author: | Ralf SussmannORCiDGND, H. J. Neusser |
|---|---|
| Frontdoor URL | https://opus.bibliothek.uni-augsburg.de/opus4/120228 |
| ISSN: | 0009-2614OPAC |
| Parent Title (English): | Chemical Physics Letters |
| Publisher: | Elsevier BV |
| Place of publication: | Amsterdam |
| Type: | Article |
| Language: | English |
| Year of first Publication: | 1994 |
| Publishing Institution: | Universität Augsburg |
| Release Date: | 2025/03/12 |
| Volume: | 221 |
| Issue: | 1-2 |
| First Page: | 46 |
| Last Page: | 52 |
| DOI: | https://doi.org/10.1016/0009-2614(94)87014-4 |
| Institutes: | Fakultät für Angewandte Informatik |
| Fakultät für Angewandte Informatik / Institut für Geographie | |
| Fakultät für Angewandte Informatik / Institut für Geographie / Lehrstuhl für Physische Geographie mit Schwerpunkt Klimaforschung | |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 55 Geowissenschaften, Geologie / 550 Geowissenschaften |
