Micrometre‐sized porous polymer beads as heterogeneous molecular catalysts
- Porous polymers have great potential as versatile, chemically stable catalyst supports. Yet, shaping of the resulting powders remains a challenge. Here, we demonstrate the use of suspension polymerisation to design micrometre-sized porous polymers beads containing metal binding sites. The good accessibility of the binding sites ensures high catalytic activity, which is demonstrated for two model reactions: photochemical CO2 reduction and transfer hydrogenation of aromatic ketones. Importantly, the shaping of the host material does not affect the catalytic activity of the active site.
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