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Self-diffusion anomalies of an odd tracer in soft-core media

  • Odd-diffusive systems, characterised by broken time-reversal and/or parity, have recently been shown to display counterintuitive features such as interaction-enhanced dynamics in the dilute limit. Here we extend the investigation to the high-density limit of an odd tracer embedded in a soft medium described by the Gaussian core model (GCM) using a field-theoretic approach based on the Dean–Kawasaki equation. Our analysis reveals that interactions can enhance the dynamics of an odd tracer even in dense systems. We demonstrate that oddness results in a complete reversal of the well-known self-diffusion (Ds) anomaly of the GCM. Ordinarily, Ds exhibits a non-monotonic trend with increasing density, approaching but remaining below the interaction-free diffusion, D0, (Ds < D0) so that Ds ↑ D0 at high densities. In contrast, for an odd tracer, self-diffusion is enhanced (Ds > D0) and the GCM anomaly is inverted, displaying Ds ↓ D0 at high densities. The transition between the standard andOdd-diffusive systems, characterised by broken time-reversal and/or parity, have recently been shown to display counterintuitive features such as interaction-enhanced dynamics in the dilute limit. Here we extend the investigation to the high-density limit of an odd tracer embedded in a soft medium described by the Gaussian core model (GCM) using a field-theoretic approach based on the Dean–Kawasaki equation. Our analysis reveals that interactions can enhance the dynamics of an odd tracer even in dense systems. We demonstrate that oddness results in a complete reversal of the well-known self-diffusion (Ds) anomaly of the GCM. Ordinarily, Ds exhibits a non-monotonic trend with increasing density, approaching but remaining below the interaction-free diffusion, D0, (Ds < D0) so that Ds ↑ D0 at high densities. In contrast, for an odd tracer, self-diffusion is enhanced (Ds > D0) and the GCM anomaly is inverted, displaying Ds ↓ D0 at high densities. The transition between the standard and reversed GCM anomaly is governed by the tracer’s oddness, with a critical oddness value at which the tracer diffuses as a free particle (Ds ≈ D0) across all densities. We validate our theoretical predictions with Brownian dynamics simulations, finding strong agreement between the them.show moreshow less

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Metadaten
Author:Pietro Luigi Muzzeddu, Erik Kalz, Andrea Gambassi, Abhinav SharmaORCiDGND, Ralf Metzler
URN:urn:nbn:de:bvb:384-opus4-1213846
Frontdoor URLhttps://opus.bibliothek.uni-augsburg.de/opus4/121384
ISSN:1367-2630OPAC
Parent Title (English):New Journal of Physics
Publisher:IOP Publishing
Place of publication:Bristol
Type:Article
Language:English
Year of first Publication:2025
Publishing Institution:Universität Augsburg
Release Date:2025/04/10
Volume:27
Issue:3
First Page:033025
DOI:https://doi.org/10.1088/1367-2630/adbdea
Institutes:Mathematisch-Naturwissenschaftlich-Technische Fakultät
Mathematisch-Naturwissenschaftlich-Technische Fakultät / Institut für Physik
Mathematisch-Naturwissenschaftlich-Technische Fakultät / Institut für Physik / Lehrstuhl für Theoretische Physik II
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 53 Physik / 530 Physik
Licence (German):CC-BY 4.0: Creative Commons: Namensnennung (mit Print on Demand)